March 17, 2003
A detailed investigation of mesoscopic magnetic and crystallographic phase separation in Ca(1-x)La(x)MnO3, 0.00<=x<=0.20, is reported. Neutron powder diffraction and DC-magnetization techniques have been used to isolate the different roles played by electrons doped into the eg level as a function of their concentration x. The presence of multiple low-temperature magnetic and crystallographic phases within individual polycrystalline samples is argued to be an intrinsic feature of the system that follows from the shifting balance between competing FM and AFM interactions as a function of temperature. FM double-exchange interactions associated with doped eg electrons are favored over competing AFM interactions at higher temperatures, and couple more strongly with the lattice via orbital polarization. These FM interactions thereby play a privileged role, even at low eg electron concentrations, by virtue of structural modifications induced above the AFM transition temperatures.
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December 9, 1999
Neutron powder diffraction measurements, combined with magnetization and resistivity data, have been carried out in the doped perovskite La$_{1-x}$Ca$_x$MnO$_3$ ($x=0.47$, 0.50, and 0.53) to elucidate the structural, magnetic, and electronic properties of the system around the composition corresponding to an equal number of Mn3+ and Mn4+. At room temperature all three samples are paramagnetic and single phase, with crystallographic symmetry Pnma. The samples then all become f...
November 4, 2005
The dc magnetization (M) and electrical resistivity (\rho) as functions of magnetic field and temperature are reported for a series of lightly electron dopedCa(1-x)La(x)MnO(3) (0<=x<=0.10) specimens for which magnetization [Phys. Rev. B {\bf 61}, 14319 (2000)] and scattering studies [Phys. Rev. B {\bf 68}, 134440 (2003)] indicate an inhomogeneous magnetic ground state composed of ferromagnetic (FM) droplets embedded in a G-type antiferromagnetic matrix. A change in the magnet...
March 21, 2004
In this article a detailed study of La$_{1-x}$Ca$_x$MnO$_3$ ($0\leq x \leq 0.23$) phase diagram using powder x-ray diffraction and magnetization measurements is presented. Unfortunately, in the related literature no properly characterized samples have been used, with consequence the smearing of the real physics in this complicated system. As the present results reveal, there are two families of samples. The first family concerns samples prepared in atmosphere ($P({\rm O}_2)=0...
June 7, 2012
The chemical influence in the phase separation phenomenon that occurs in perovskite manganites is discussed by means of ab initio calculations. Supercells have been used to simulate a phase separated state, that occurs at Ca concentrations close to the localized to itinerant crossover. We have first considered a model with two types of magnetic ordering coexisting within the same compound. This is not stable. However, a non-isotropic distribution of chemical dopants is found ...
March 17, 2003
Neutron measurements on Ca{1-x}La{x}MnO3 (0.00 <= x <= 0.20) reveal the development of a liquid-like spatial distribution of magnetic droplets of average size ~10 Angstroms, the concentration of which is proportional to x (one cluster per ~60 doped electrons). In addition, a long-range ordered ferromagnetic component is observed for ~0.05 < x < ~0.14. This component is perpendicularly coupled to the simple G-type antiferromagnetic (G-AFM) structure of the undoped compound, wh...
April 8, 2011
We demonstrate that magnetic phase separation and competing spin order in the colossal magnetoresistive (CMR) manganites can be directly explored via tuning strain in bulk samples of nanocrystalline La$_{1-x}$Ca$_x$MnO$_3$. Our results show that strain can be reversibly frozen into the lattice in order to stabilize coexisting antiferromagnetic domains within the nominally ferromagnetic metallic state of La$_{5/8}$Ca$_{3/8}$MnO$_3$. The measurement of tunable phase separation ...
May 15, 2000
A systematic study of phase separation effects in polycrystalline La_0.5 Ca_0.5 Mn O_3 obtained under different thermal treatments is reported. Samples with average grain size ranging from 200 to 1300 nm were studied. Magnetic and electrical measurements show quantitative differences among samples in their low temperature behavior. indicating that the fraction of the ferromagnetic (FM) phase gradually decreases as the grain size increase. Percolation of the FM phase in sample...
August 15, 2001
Measurements of the specific heat on the system Ca$_{1-x}$La$_{x}$MnO$_{3}$ (% $x\leq 0.10$) are reported. Particular attention is paid to the effect that doping the parent compound with electrons by substitution of La for Ca has on the magnetic ground state. The high ($T>40$ K) temperature data reveals that doping decreases $T_{N}$ from 122 K for the undoped sample to 103 K for $x=0.10$. The low temperature ($T<20$ K) heat capacity data is consistent with phase separation. T...
August 11, 2007
A temperature-dependent EXAFS investigation of La{1-x}Ca{x}MnO3 is presented for the concentration range that spans the ferromagnetic-insulator (FMI) to ferromagnetic-metal (FMM) transition region, x = 0.16-0.22. The samples are insulating for x = 0.16-0.2 and show a metal/insulator transition for x = 0.22. All samples are ferromagnetic although the saturation magnetization for the 16% Ca sample is only ~ 70% of the expected value at 0.4T. We find that the FMI samples have si...
May 6, 2011
The magnetic interactions in La{0.70}Ca{0.30}Mn{1-x}Cr{x}O{3} (x = 0.15, 0.50 and 0.70) are investigated by x-ray absorption spectroscopy (XAS), x-ray magnetic circular dichroism (XMCD), high-resolution x-ray powder diffraction, and bulk magnetization measurements. XAS in the Mn and Cr L{2,3} edges support stable single valent Cr{3+} ions and a varying Mn valence state with x, while the O K edge XAS spectrum reveals local maxima in the O 2p density of states close to the Ferm...