March 31, 2005
We study the mean-field approximation of Quantum Electrodynamics, by means of a thermodynamic limit. The QED Hamiltonian is written in Coulomb gauge and does not contain any normal-ordering or choice of bare electron/positron subspaces. Neglecting photons, we define properly this Hamiltonian in a finite box $[-L/2;L/2)^3$, with periodic boundary conditions and an ultraviolet cut-off $\Lambda$. We then study the limit of the ground state (i.e. the vacuum) energy and of the minimizers as $L$ goes to infinity, in the Hartree-Fock approximation. In case with no external field, we prove that the energy per volume converges and obtain in the limit a translation-invariant projector describing the free Hartree-Fock vacuum. We also define the energy per unit volume of translation-invariant states and prove that the free vacuum is the unique minimizer of this energy. In the presence of an external field, we prove that the difference between the minimum energy and the energy of the free vacuum converges as $L$ goes to infinity. We obtain in the limit the so-called Bogoliubov-Dirac-Fock functional. The Hartree-Fock (polarized) vacuum is a Hilbert-Schmidt perturbation of the free vacuum and it minimizes the Bogoliubov-Dirac-Fock energy.
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