Entropic Functionals in Quantum Statistical Mechanics

The celebrated Evans-Searles, respectively Gallavotti-Cohen, fluctuation theorem concerns certain universal statistical features of the entropy production rate of a classical system in a transient, respectively steady, state. In this paper, we consider and compare several possible extensions of these fluctuation theorems to quantum systems. In addition to the direct two-time measurement approach whose discussion is based on (LMP 114:32 (2024)), we discuss a variant where meas...

In this work we will show that there exists a fundamental difference between microscopic quantum thermodynamics and macroscopic classical thermodynamics. It will be proved that the entropy production in quantum thermodynamics always vanishes for both closed and open quantum thermodynamic systems. This novel and very surprising result is derived based on the genuine reasoning Clausius used to establish the science of thermodynamics in the first place. This result will interest...

We compare two proposals for the dynamical entropy of quantum deterministic systems (CNT and AFL) by studying their extensions to classical stochastic systems. We show that the natural measurement procedure leads to a simple explicit expression for the stochastic dynamical entropy with a clear information-theoretical interpretation. Finally, we compare our construction with other recent proposals.

In the past several years, observational entropy has been developed as both a (time-dependent) quantum generalization of Boltzmann entropy, and as a rather general framework to encompass classical and quantum equilibrium and non-equilibrium coarse-grained entropy. In this paper we review the construction, interpretation, most important properties, and some applications of this framework. The treatment is self-contained and relatively pedagogical, aimed at a broad class of res...

We present here a set of lecture notes on quantum thermodynamics and canonical typicality. Entanglement can be constructively used in the foundations of statistical mechanics. An alternative version of the postulate of equal a priori probability is derived making use of some techniques of convex geometry

The formulation of quantum mechanics within the framework of entropic dynamics is extended to the domain of relativistic quantum fields. The result is a non-dissipative relativistic diffusion in the infinite dimensional space of field configurations. On extending the notion of entropic time to the relativistic regime we find that the field fluctuations provide the clock that sets the scale of duration. We also find that the usual divergences that affect all quantum field theo...

The most fundamental properties of quantum entropy are derived by considering the union of two ensembles. We discuss the limits these properties put on an entropy measure and obtain that they uniquely determine the form of the entropy functional up to normalisation. In particular, the result implies that all other properties of quantum entropy may be derived from these first principles.

We extend classical coarse-grained entropy, commonly used in many branches of physics, to the quantum realm. We find two coarse-grainings, one using measurements of local particle numbers and then total energy, and the second using local energy measurements, which lead to an entropy that is defined outside of equilibrium, is in accord with the thermodynamic entropy for equilibrium systems, and reaches the thermodynamic entropy in the long-time limit, even in genuinely isolate...

We suggest that the framework of quantum information theory, which has been developing rapidly in recent years due to intense activity in quantum computation and quantum communication, is a reasonable starting point to study non-equilibrium quantum statistical phenomena. As an application, we discuss the non-equilibrium quantum thermodynamics of black hole formation and evaporation.

We review the derivation of quantum theory as an application of entropic methods of inference. The new contribution in this paper is a streamlined derivation of the Schr\"odinger equation based on a different choice of microstates and constraints.