Work extraction and thermodynamics for individual quantum systems

In recent years we have witnessed a concentrated effort to make sense of thermodynamics for small-scale systems. One of the main difficulties is to capture a suitable notion of work that models realistically the purpose of quantum machines, in an analogous way to the role played, for macroscopic machines, by the energy stored in the idealisation of a lifted weight. Despite of several attempts to resolve this issue by putting forward specific models, these are far from capturi...

We consider locally thermal states (for two qubits) with certain amount of quantum entanglement present between them. Unlike previous protocols we show how work can be extracted by performing local unitary operations on this state by allowing those two qubits to interact with thermal baths of different temperatures, thereby gradually removing the entanglement between them till they reach a direct product state. Also we demonstrate that, further work can be extracted from this...

The interplay between quantum-mechanical properties, such as coherence, and classical notions, such as energy, is a subtle topic at the forefront of quantum thermodynamics. The traditional Carnot argument limits the conversion of heat to work; here we critically assess the problem of converting coherence to work. Through a careful account of all resources involved in the thermodynamic transformations within a fully quantum-mechanical treatment, we show that there exist therma...

This paper considers work extraction from a quantum system to a work storage system (or weight) following reference [1]. An alternative approach is here developed that relies on the comparison of subspace dimensions without a need to introduce thermo-majorisation used previously. Optimal single shot work for processes where a weight transfers from (a) a single energy level to another single energy level is then re-derived. In addition we discuss the final state of the system ...

Constraints on work extraction are fundamental to our operational understanding of the thermodynamics of both classical and quantum systems. In the quantum setting, finite-time control operations typically generate coherence in the instantaneous energy eigenbasis of the dynamical system. Thermodynamic cycles can, in principle, be designed to extract work from this non-equilibrium resource. Here, we isolate and study the quantum coherent component to the work yield in such pro...

We consider a generalisation of thermodynamics that deals with multiple conserved quantities at the level of individual quantum systems. Each conserved quantity, which, importantly, need not commute with the rest, can be extracted and stored in its own battery. Unlike in standard thermodynamics, where the second law places a constraint on how much of the conserved quantity (energy) that can be extracted, here, on the contrary, there is no limit on how much of any individual c...

A pair of two-level systems initially prepared in different thermal states and coupled to an external reversible work source, do not in general reach a common temperature at the end of a unitary work extraction process. We define an effective temperature for the final nonequilibrium but passive state of the bipartite quantum system and analyse its properties.

We consider continuously monitored quantum systems and introduce definitions of work and heat along individual quantum trajectories that are valid for coherent superpositions of energy eigenstates. We use these quantities to extend the first and second laws of stochastic thermodynamics to the quantum domain. We illustrate our results with the case of a weakly measured driven two-level system and show how to distinguish between quantum work and heat contributions. We finally e...

This extended abstract contains an outline of the work reported at the conference IQIS2018. We show that it is possible to exploit a thermalization process to extract work from a resource system $R$ to a bipartite system $S$. To do this, we propose a simple protocol in a general setting in the presence of a single bath at temperature $T$ and then examine it when $S$ is described by the quantum Rabi model at $T=0$. We find the theoretical bounds of the protocol in the general ...

A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further, engines with lesser fluctuation produce a lesser amount of deterministic work. Hence, the heat-to-work conversion efficiency stays well below the Carnot efficiency. Here we overcome this limitation and attain Carnot efficiency in the one-shot f...