July 1, 2015
This article sets up a formalism to describe stochastic thermodynamics for driven out-of-equilibrium open quantum systems. A stochastic Schr\"odinger equation allows to construct quantum trajectories describing the dynamics of the system state vector in presence of an eventually monitored environment. Thermodynamic quantities are defined at the single quantum trajectory level, independently of any energy measurement, at any time of the protocol. We thereby identify coherent contributions, without classical counterparts, leading to quantum fluctuations of thermodynamic quantities. This formalism eventually leads to central fluctuation theorems for entropy, extending in the quantum regime results obtained in classical stochastic thermodynamics. The thermal imprint of coherences on a simple implementation of Jarzynski equality is investigated, opening avenues for a thermodynamic approach to decoherence.
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March 23, 2016
This article sets up a new formalism to investigate stochastic thermodynamics of out-of-equilibrium quantum systems, where stochasticity primarily comes from quantum measurement. In the absence of any bath, we define a purely quantum component to heat exchange, that corresponds to energy fluctuations induced by measurement back-action. By providing a central position to quantum measurement, our formalism bridges the gap between quantum optics and quantum thermodynamics: Therm...
December 3, 2021
The thermodynamics of quantum systems driven out of equilibrium has attracted increasing attention in last the decade, in connection with quantum information and statistical physics, and with a focus on non-classical signatures. While a first approach can deal with average thermodynamics quantities over ensembles, in order to establish the impact of quantum and environmental fluctuations during the evolution, a continuous quantum measurement of the open system is required. He...
May 29, 2013
For classical nonequilibrium systems, the separation of the total entropy production into the adiabatic and nonadiabatic contributions is useful for understanding irreversibility in nonequilibrium thermodynamics. In this article, we formulate quantum analogs for driven open quantum systems describable by quantum jump trajectories by applying a quantum stochastic thermodynamics. Our main conclusions are based on a quantum formulation of the local detailed balance condition.
July 8, 2016
This article sets up a new formalism to investigate stochastic thermodynamics in the quantum regime, where stochasticity and irreversibility primarily come from quantum measurement. In the absence of any bath, we define a purely quantum component to heat exchange, that corresponds to energy fluctuations caused by measurement back-action. Energetic and entropic signatures of measurement induced irreversibility are then investigated for canonical experiments of quantum optics, ...
May 21, 2018
Quantum open systems evolve according to completely positive, trace preserving maps acting on the density operator, which can equivalently be unraveled in term of so-called quantum trajectories. These stochastic sequences of pure states correspond to the actual dynamics of the quantum system during single realizations of an experiment in which the system's environment is monitored. In this chapter, we present an extension of stochastic thermodynamics to the case of open quant...
December 12, 2011
Stochastic methods are ubiquitous to a variety of fields, ranging from Physics to Economy and Mathematics. In many cases, in the investigation of natural processes, stochasticity arises every time one considers the dynamics of a system in contact with a somehow bigger system, an environment, that is considered in thermal equilibrium. Any small fluctuation of the environment has some random effect on the system. In Physics, stochastic methods have been applied to the investiga...
May 29, 2013
Employing the stochastic wave function method, we study quantum features of stochastic entropy production in nonequilibrium processes of open systems. It is demonstarted that continuous measurements on the environment introduce an additional, non-thermal contribution to the entropy flux, which is shown to be a direct consequence of quantum fluctuations. These features lead to a quantum definition of single trajectory entropy contributions, which accounts for the difference be...
September 3, 2015
Classical thermodynamics is unrivalled in its range of applications and relevance to everyday life. It enables a description of complex systems, made up of microscopic particles, in terms of a small number of macroscopic quantities, such as work and entropy. As systems get ever smaller, fluctuations of these quantities become increasingly relevant, prompting the development of stochastic thermodynamics. Recently we have seen a surge of interest in exploring the quantum regime...
August 24, 2024
The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasi-static process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the me...
September 30, 2011
In this paper we present a first-principles analysis of the nonequilibrium work distribution and the free energy difference of a quantum system interacting with a general environment (with arbitrary spectral density and for all temperatures) based on a well-understood micro-physics (quantum Brownian motion) model under the conditions stipulated by the Jarzynski equality [C. Jarzynski, Phys. Rev. Lett. 78, 2690 (1997)] and Crooks' fluctuation theorem [G. E. Crooks, Phys. Rev. ...