From Quantum Dynamics to the Second Law of Thermodynamics

We analyze an autonomous micro-engine as a closed quantum mechanical system, including the work it performs and the fuel it consumes. Our model system shows by example that it is possible to transfer energy steadily and spontaneously between fast and slow degrees of freedom, in analogy to the way combustion engines convert chemical energy into work. Having shown this possibility, we observe close analogies between the closed-system quantum dynamics of our micro-engine and the...

In recent years we have witnessed a concentrated effort to make sense of thermodynamics for small-scale systems. One of the main difficulties is to capture a suitable notion of work that models realistically the purpose of quantum machines, in an analogous way to the role played, for macroscopic machines, by the energy stored in the idealisation of a lifted weight. Despite of several attempts to resolve this issue by putting forward specific models, these are far from capturi...

Thermodynamics is traditionally concerned with systems comprised of a large number of particles. Here we present a framework for extending thermodynamics to individual quantum systems, including explicitly a thermal bath and work-storage device (essentially a `weight' that can be raised or lowered). We prove that the second law of thermodynamics holds in our framework, and give a simple protocol to extract the optimal amount of work from the system, equal to its change in fre...

Work extraction from the Gibbs ensemble by a cyclic operation is impossible, as represented by the second law of thermodynamics. On the other hand, the eigenstate thermalization hypothesis (ETH) states that just a single energy eigenstate can describe a thermal equilibrium state. Here we attempt to unify these two perspectives and investigate the second law at the level of individual energy eigenstates, by examining the possibility of extracting work from a single energy eige...

Dissipative quantum systems are frequently described within the framework of the so-called "system-plus-reservoir" approach. In this work we assign their description to the Maximum Entropy Formalism and compare the resulting thermodynamic properties with those of the well - established approaches. Due to the non-negligible coupling to the heat reservoir, these systems are non-extensive by nature, and the former task may require the use of non-extensive parameter dependent inf...

In this work we study how the non-Markovian character of the dynamics can affect the thermodynamic performance of a quantum thermal engine, by analysing the maximum power output of Carnot and Otto cycles departing from the quasi-static and infinite-time-thermalization regime respectively, introducing techniques for their control optimization in general dynamical models. In our model, non-Markovianity is introduced by allowing some degrees of freedom of the reservoirs to be ta...

For a two-level quantum mechanical system, we derive microscopically the exact expression for the fluctuation of microscopic work in a multi-step non-equilibrium process, and we rigorously prove that in an isothermal process, the fluctuation is vanishingly small, and the most probabilistic work just equals to the difference of the free energy. Our study demonstrates that the convergence of the microscopic work in the isothermal process is due to the nature of isothermal proce...

We revisit the problem of work extraction from a system in contact with a heat bath to a work storage system, and the reverse problem of state formation from a thermal system state in single-shot quantum thermodynamics. A physically intuitive and mathematically simple approach using only elementary majorization theory and matrix analysis is developed, and a graphical interpretation of the maximum extractable work, minimum work cost of formation, and corresponding single-shot ...

The minimal work principle states that work done on a thermally isolated equilibrium system is minimal for adiabatically slow (reversible) realization of a given process. This principle, one of the formulations of the second law, is studied here for finite (possibly large) quantum systems interacting with macroscopic sources of work. It is shown to be valid as long as the adiabatic energy levels do not cross. If level crossing does occur, counter examples are discussed, showi...

Recently Sagawa and Ueda [Phys. Rev. Lett. 100, 080403 (2008)] derived a bound on the work that can be extracted from a quantum system with the use of feedback control. They left open the question of whether this bound could be achieved for every measurement that could be made by the controller. We show that it can, and that this follows straightforwardly from recent work on Maxwell's demon by Alicki et al. [Open Syst. Inform. Dynam. 11, 205 (2004)], for both discrete and con...