Second virial coefficient for a d-dimensional Lennard-Jones (2n-n) system

The equation of state for an ideal gas is simple, which is $P=nk_{\rm B}T$. In the case of imperfect gases where mutual interactions among the constituents are important, pressure $P$ can be expressed as the series expansion of density $n$ with appropriate coefficients, known as virial coefficients $B_m$. In this paper, we have obtained the first four virial coefficients for a model interaction potential $\Phi(r)$ using multidimensional Monte-Carlo integration and importance ...

The well-known results concerning a dilute Bose gas with the short-range repulsive interaction should be reconsidered due to a thermodynamic inconsistency of the method being basic to much of the present understanding of this subject. The aim of our paper is to propose a new way of treating the dilute Bose gas with an arbitrary strong interaction. Using the reduced density matrix of the second order and a variational procedure, this way allows us to escape the inconsistency m...

Exact results are given for the fourth virial coefficient of hard spheres in even dimensions up through 12. The fifth and sixth virial coefficients are numerically computed for dimensions 2 through 50 and it is found that the sixth virial coefficient is negative for D >= 6. Numerical studies are made of the contributing Ree Hoover diagrams up to order 17. It is found for D >= 3 that for large order a class of diagrams we call "loose packed" dominates and the rate of growth of...

The recent theoretical prediction by Maimbourg and Kurchan [arXiv:1603.05023] that for regular pair-potential systems the virial potential-energy correlation coefficient increases towards unity as the dimension $d$ goes to infinity is investigated for the standard 12-6 Lennard-Jones fluid. This is done by computer simulations for $d=2,3,4$ going from the critical point along the critical isotherm/isochore to higher density/temperature. In all cases the virial potential-energy...

The van-der-Waals version of the second virial coefficient is not far from being exact if the model parameters are appropriately chosen. It is shown how the van-der-Waals resemblance originates from the interplay of thermal averaging and superposition of scattering phase shift contributions. The derivation of the two parameters from the quantum virial coefficient reveals a fermion-boson symmetry in non-ideal quantum gases. Numerical details are worked out for the Helium quant...

In a recent paper entitled "High temperature expansion applied to fermions near Feshbach resonance" (Phys. Rev. Lett. 92, 160404 (2004)), Ho and Muller have demonstrated a remarkable similarity between its high and low temperature properties at resonance. The quantum second virial coefficient plays a crucial role in their analysis, and has a universal value at resonance. In this paper, we explore the connection between the quantum and classical second virial coefficients, and...

In this note we revisit the recent developments concerning rigorous results on the virial series of a continuous system of classical particles interacting via a stable and tempered pair potential and we provide new lower bounds for its convergence radius when the potential has a strictly positive stability constant. As an application we obtain a new estimate for the convergence radius of the virial series of the Lennard-Jones gas which improves sensibly previous estimates pre...

The virial expansion of a gas is a correction to the ideal gas law that is usually discussed in advanced courses in statistical mechanics. In this note we outline this derivation in a manner suitable for advanced undergraduate and introductory graduate classroom presentations. We introduce a physically meaningful interpretation of the virial expansion that has heretofore escaped attention, by showing that the virial series is actually an expansion in a parameter that is the r...

The well-known results concerning a dilute Bose gas with the short-range repulsive interaction should be reconsidered due to a thermodynamic inconsistency of the method being basic to much of the present understanding of this subject and nonrelevant behaviour of the pair distribution function at small boson separations. The aim of our paper is to propose a new way of treating the dilute Bose gas with an arbitrary strong interaction. Using the reduced density matrix of the sec...

Recent values for virial coefficients up to B12, when expressed in powers of density relative to maximum close packing,lead to a closed equation-of-state for the equilibrium fluid. The series obtained converges for all densities;it becomes negative and diverges to a negative pole at maximum packing. MD data for 64000 spheres in the metastable region shows the virial pressure begins to deviate at the fluid freezing density.