Validity of the second law in nonextensive quantum thermodynamics

Gibbs-Boltzmann entropy leads to systems that have a strong dependence on initial conditions. In reality, most materials behave quite independently of initial conditions. Nonextensive entropy or Tsallis entropy leads to nonextensive statistical mechanics. In this paper, we calculate the Tsallis form of Clausius inequality and then determine the upper bound for extracting work from the small system in the nonextensive statistical mechanics with mutual information. In the follo...

This paper has been withdrawn by the author. For the reason, see the bottom paragraph of this abstract. By generalizing Tasaki's work on the second law of thermodynamics for an adiabatic process between two equilibrium states of a macroscopic quantum compound system, we obtain an extension of the second law to a transient adiabatic process that takes a macroscopic quantum compound system consisting of a system of interest and two heat reservoirs from an initial equilibrium ...

We review the fundamental properties of the quantum relative entropy for finite-dimensional Hilbert spaces. In particular, we focus on several inequalities that are related to the second law of thermodynamics, where the positivity and the monotonicity of the quantum relative entropy play key roles; these properties are directly applicable to derivations of the second law (e.g., the Clausius inequality). Moreover, the positivity is closely related to the quantum fluctuation th...

The second law of classical thermodynamics, based on the positivity of the entropy production, only holds for deterministic processes. Therefore the Second Law in stochastic quantum thermodynamics may not hold. By making a fundamental connection between thermodynamics and information theory we will introduce a new way of defining the Second Law which holds for both deterministic classical and stochastic quantum thermodynamics. Our work incorporates information well into the S...

In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this paper, we investigate how the relaxation toward equilibrium is made possible through interactions that do not lead to significant exchange of energy, and argue for the validity of the second law of thermodynamics at the microscopic scale.

A proof of the quantum $H$-theorem taking into account nonextensive effects on the quantum entropy $S^Q_q$ is shown. The positiveness of the time variation of $S^Q_q$ combined with a duality transformation implies that the nonextensive parameter $q$ lies in the interval [0,2]. It is also shown that the equilibrium states are described by quantum $q$-power law extensions of the Fermi-Dirac and Bose-Einstein distributions. Such results reduce to the standard ones in the extensi...

The second law of thermodynamics tells us which state transformations are so statistically unlikely that they are effectively forbidden. Its original formulation, due to Clausius, states that "Heat can never pass from a colder to a warmer body without some other change, connected therewith, occurring at the same time". The second law applies to systems composed of many particles interacting; however, we are seeing that one can make sense of thermodynamics in the regime where ...

In this work we will show that there exists a fundamental difference between microscopic quantum thermodynamics and macroscopic classical thermodynamics. It will be proved that the entropy production in quantum thermodynamics always vanishes for both closed and open quantum thermodynamic systems. This novel and very surprising result is derived based on the genuine reasoning Clausius used to establish the science of thermodynamics in the first place. This result will interest...

Bento \textit{et al.} [Phys. Rev. E 91, 022105 (2015)] state that the Tsallis entropy violates the third law of thermodynamics for $q \leq 0$ and $0<q<1$. We show that their results are valid only for $q \geq 1$, since there is no distribution maximizing the Tsallis entropy for the intervals $q \leq 0$ and $0<q<1$ compatible with the system energy expression.

It is shown that the laws of thermodynamics are extremely robust under generalizations of the form of entropy. Using the Bregman-type relative entropy, the Clausius inequality is proved to be always valid. This implies that thermodynamics is highly universal and does not rule out consistent generalization of the maximum entropy method.