Exact Maxwell-Boltzmann, Bose-Einstein and Fermi-Dirac Statistics

We consider a system composed of a fixed number of particles with total energy smaller or equal to some prescribed value. The particles are non-interacting, indistinguishable and distributed over fixed number of energy levels. The energy levels are degenerate and degeneracy is a function of the number of particles. Three cases of the degeneracy function is considered. It can increase with either the same rate as the number of particles or slower, or faster. We find useful pro...

The violation of the Pauli principle has been surmised in several models of the Fractional Exclusion Statistics and successfully applied to several quantum systems. In this paper, a classical alternative of the exclusion statistics is studied using the maximum entropy methods. The difference between the Bose-Einstein statistics and the Maxwell-Boltzmann statistics is understood in terms of a separable quantity, namely the degree of indistinguishability. Starting from the usua...

Here we have discussed on Fermi-Dirac statistics, in particular, on its brief historical progress, derivation, consequences, applications, etc. Importance of Fermi-Dirac statistics has been discussed even in connection with the current progresses in science. This article is aimed mainly for undergraduate and graduate students.

The combinatorial basis of entropy, given by Boltzmann, can be written $H = N^{-1} \ln \mathbb{W}$, where $H$ is the dimensionless entropy, $N$ is the number of entities and $\mathbb{W}$ is number of ways in which a given realization of a system can occur (its statistical weight). This can be broadened to give generalized combinatorial (or probabilistic) definitions of entropy and cross-entropy: $H=\kappa (\phi(\mathbb{W}) +C)$ and $D=-\kappa (\phi(\mathbb{P}) +C)$, where $\m...

The paper analyzes the entropy of a system composed by non-interacting and indistinguishable particles whose quantum state numbers are modelled as independent and identically distributed classical random variables. The crucial observation is that, under this assumption, whichever is the number of particles that constitute the system, the occupancy numbers of system's quantum (micro)states are multinomially distributed. This observation leads to an entropy formula for the phys...

Equations are obtained for the quantum distribution functions over discrete states in systems of non-interacting fermions and bosons with an arbitrary, including small, number of particles. The case of systems with two levels is considered in detail. The temperature dependences of entropy, heat capacities and pressure in two-level Fermi and Bose systems are calculated for various multiplicities of degeneracy of levels.

The division by N! in the expression of statistical entropy is usually justified to students by the statement that classical particles should be counted as indistinguishable. Sometimes, quantum indistinguishability is invoked to explain it. In this paper, we try to clarify the issue starting from Clausius thermodynamical entropy and deriving from it Boltzmann statistical entropy for the ideal gas. This approach appears interesting for two reasons: Firstly, it provides a direc...

Quasi-set theory provides us a mathematical background for dealing with collections of indistinguishable elementary particles. In this paper, we show how to obtain the usual statistics (Maxwell-Boltzmann, Bose-Einstein, and Fermi-Dirac) into the scope of quasi-set theory. We also show that, in order to derive Maxwell-Boltzmann statistics, it is not necessary to assume that the particles are distinguishable. In other words, Maxwell-Boltzmann statistics is possible even in an e...

We overwiev the properties of a quantum gas of particles with the intermediate statistics defined by Haldane. Although this statistics has no direct connection to the symmetry of the multiparticle wave function, the statistical distribution function interpolates continuously between the Fermi-Dirac and the Bose-Einstein limits. We present an explicit solution of the transcendental equation for the didtribution function in a general case, as well as determine the thermodynamic...

A pedagogical derivation of statistical mechanics from quantum mechanics is provided, by means of open quantum systems. Besides, a new definition of Boltzmann entropy for a quantum closed system is also given to count microstates in a way consistent with the superposition principle. In particular, this new Boltzmann entropy is a constant that depends only on the dimension of the system's relevant Hilbert subspace. Finally, thermodynamics for quantum systems is investigated fo...