Self-organization with equilibration: a model for the intermediate phase in rigidity percolation

Our general subject is the emergence of phases, and phase transitions, in large networks subjected to a few variable constraints. Our main result is the analysis, in the model using edge and triangle subdensities for constraints, of a sharp transition between two phases with different symmetries, analogous to the transition between a fluid and a crystalline solid.

Bulk glass formation occurs over a very small part of phase space, and "good" glasses (which form even at low quench rates ~ 10K/sec) select an even smaller part of that accessible phase space. An axiomatic theory provides the physical basis of glass formation, and identifies these sweet spots of glass formation with existence of rigid but stress-free networks for which experimental evidence is rapidly emerging. Recently, theory and experiment have come together to show that ...

Signatures of glassy dynamics have been identified experimentally for a rich variety of materials in which molecular networks provide rigidity. Here we present a theoretical framework to study the glassy behavior of both passive and active network materials. We construct a general microscopic network model that incorporates nonlinear elasticity of individual filaments and steric constraints due to crowding. Based on constructive analogies between structural glass forming liqu...

We reveal significant qualitative differences in the rigidity transition of three types of disordered network materials: randomly diluted spring networks, jammed sphere packings, and stress-relieved networks that are diluted using a protocol that avoids the appearance of floppy regions. The marginal state of jammed and stress-relieved networks are globally isostatic, while marginal randomly diluted networks show both overconstrained and underconstrained regions. When a single...

In this article we give an in depth overview of the recent advances in the field of equilibrium networks. After outlining this topic, we provide a novel way of defining equilibrium graph (network) ensembles. We illustrate this concept on the classical random graph model and then survey a large variety of recently studied network models. Next, we analyze the structural properties of the graphs in these ensembles in terms of both local and global characteristics, such as degree...

We study how the thermodynamic properties of the Triangular Plaquette Model (TPM) are influenced by the addition of extra interactions. The thermodynamics of the original TPM is trivial, while its dynamics is glassy, as usual in Kinetically Constrained Models. As soon as we generalize the model to include additional interactions, a thermodynamic phase transition appears in the system. The additional interactions we consider are either short ranged, forming a regular lattice i...

The self-organized dopant percolative filamentary model, entirely orbital in character (no fictive spins), explains chemical trends in superconductive transition temperatures Tc, assuming that Cooper pairs are formed near dopants because attractive electron-phonon interactions outweigh repulsive Coulomb interactions. According to rules previously used successfully for network glasses, the host networks are marginally stable mechanically. The high Tc's are caused by softening ...

We consider a network, bonds of which are being sequentially removed; that is done at random, but conditioned on the system remaining connected (Self-Repairing Bond Percolation SRBP). This model is the simplest representative of a class of random systems for which forming of isolated clusters is forbidden. It qualitatively describes the process of fabrication of artificial porous materials and degradation of strained polymers. We find a phase transition at a finite concentrat...

The description of thermodynamic phase transitions in terms of percolation transitions of suitably defined clusters has a long tradition and boasts a number of important successes, the most prominent ones being in ferromagnetic lattice models. Spin glasses and other frustrated systems are not among them as the clusters of aligned spins usually considered in this context start to percolate in the disordered phase and hence fail to indicate the onset of ordering. In this mini-r...

During the past two decades, percolation has long served as a basic paradigm for network resilience, community formation and so on in complex systems. While the percolation transition is known as one of the most robust continuous transitions, the percolation transitions occurring in complex systems are often of different types such as discontinuous, hybrid, and infinite-order phase transitions. Thus, percolation has received considerable attention in network science community...