Comment on ``Large Slip of Aqueous Liquid Flow over a Nanoengineered Superhydrophobic Surface'' by C-H Choi and C Kim

Recent experiments (Zhu & Granick (2001) Phys. Rev. Lett. 87 096105) have measured a large shear dependent fluid slip at partially wetting fluid-solid surfaces. We present a simple model for such slip, motivated by the recent observations of nanobubbles on hydrophobic surfaces. The model considers the dynamic response of bubbles to change in hydrodynamic pressure due to the oscillation of a solid surface. Both the compression and diffusion of gas in the bubbles decrease the f...

Super-hydrophobic array of grooves containing trapped gas (stripes), have the potential to greatly reduce drag and enhance mixing phenomena in microfluidic devices. Recent work has focused on idealized cases of stick-perfect slip stripes, with limited guidance. Here, we analyze the experimentally relevant situation of a pressure-driven flow past striped slip-stick surfaces with arbitrary local slip at the gas sectors. We derive analytical formulas for maximal (longitudinal) a...

In this Letter, the falling of super-hydrophobic spheres is investigated experimentally at low Reynolds numbers. In particular, we show that super-hydrophobic coatings become ineffective at reducing drag unlike predicted by theoretical and numerical approaches. A time scale analysis describing both Marangoni-induced stresses and air/liquid interface deformation shows that these mechanisms are unlikely to account for the slippage effect disappearance observed in our study. Ins...

We report results of direct measurements of velocity profiles in a microchannel with hydrophobic and hydrophilic walls, using a new high precision method of double-focus spacial fluorescence cross-correlation under a confocal microscope. In the vicinity of both walls the measured velocity profiles do not turn to zero by giving a plateau of constant velocity. This apparent slip is proven to be due to a Taylor dispersion, an augmented by shear diffusion of nanotracers in the di...

At finite Reynolds numbers particles migrate across flow streamlines to their equilibrium positions in microchannels. Such a migration is attributed to an inertial lift force, and it is well-known that the equilibrium location of neutrally-buoyant particles is determined only by their size and the Reynolds number. Here we demonstrate that the decoration of a bottom wall of the channel by superhydrophobic grooves provides additional possibilities for manipulation of neutrally-...

Interfacial hydrodynamic slippage of water depends on both on surface chemistry and roughness. This study tries to connect the effect of chemical property and the physical structure of the surface on the interfacial slippage of water. By performing molecular dynamics simulations (MDS) of Couette flow of water molecules over a reduced Lennard-Jones (LJ) surface, the velocity profile is obtained and extrapolated to get the slip lengths. The slip lengths are measured for various...

It has been suggested that superhydrophobic surfaces, due to the presence of a no-shear zone, can greatly enhance transport of surface charges, leading to a considerable increase in the streaming potential. This could find potential use in micro-energy harvesting devices. In this paper, we show using analytical and numerical methods, that when a streaming potential is generated in such superhydrophobic geometries, the reverse electro-osmotic flow and hence current generated b...

Superhydrophobic surfaces reduce drag by combining hydrophobicity and roughness to trap gas bubbles in a micro- and nanoscopic texture. Recent work has focused on specific cases, such as striped grooves or arrays of pillars, with limited theoretical guidance. Here, we consider the experimentally relevant limit of thin channels and obtain rigorous bounds on the effective slip length for any two-component (e.g. low-slip and high-slip) texture with given area fractions. Among al...

The article demonstrates that the internal circulation velocity and patterns in sessile droplets on superhydrophobic surfaces is governed by the surface curvature. Particle Image Velocimetry reveals that increasing convexity deteriorates the advection velocity whereas concavity augments it. A scaling model based on the effective curvature modulated change in wettability can predict the phenomenon, but weakly. Potential flow theory is appealed to and the curvatures are approxi...

Liquid-gas-liquid interfaces stabilized by hydrophobic beads behave as ball bearings under shear and exhibit a giant slip. Using a scaling analysis and molecular dynamics simulations we predict that, when the contact angle theta between the beads and the liquid is large, the slip length diverges as R rho(-1) (pi -theta)(-3) where R is the bead radius, and theta is the bead density. DOI: 10.1103/PhysRevLett.110.104504