Scaling Model of Annihilation-Diffusion Kinetics for Charged Particles with Long-Range Interactions

In this article we review the problem of reaction annihilation $A+A \rightarrow \emptyset$ on a real lattice in one dimension, where $A$ particles move ballistically in one direction with a discrete set of possible velocities. We first discuss the case of pure ballistic annihilation, that is a model in which each particle moves simultaneously at constant speed. We then review ballistic annihilation with superimposed diffusion in one dimension. This model consists of diffusing...

We address the two-dimensional bimolecular annihilation reaction $A + A \to \emptyset$ in the presence of random impurities. Impurities with sufficiently long-ranged interaction energies are known to lead to anomalous diffusion, $<r^2(t)> \sim t^{1-\delta}$, in the absence of reaction. Applying renormalization group theory to a field theoretic description of this reaction, we find that this disorder also leads to anomalous kinetics in the long time limit: $c(t) \sim t^{\delta...

The kinetics of the q species pair annihilation reaction (A_i + A_j -> 0 for 1 <= i < j <= q) in d dimensions is studied by means of analytical considerations and Monte Carlo simulations. In the long-time regime the total particle density decays as rho(t) ~ t^{- alpha}. For d = 1 the system segregates into single species domains, yielding a different value of alpha for each q; for a simplified version of the model in one dimension we derive alpha(q) = (q-1) / (2q). Within mea...

A diffusion-limited annihilation process, A+B->0, with species initially separated in space is investigated. A heuristic argument suggests the form of the reaction rate in dimensions less or equal to the upper critical dimension $d_c=2$. Using this reaction rate we find that the width of the reaction front grows as $t^{1/4}$ in one dimension and as $t^{1/6}(\ln t)^{1/3}$ in two dimensions.

Using event-driven molecular dynamics we study one- and two-dimensional ballistic annihilation. We estimate exponents $\xi$ and $\gamma$ that describe the long-time decay of the number of particles ($n(t)\sim t^{-\xi}$) and of their typical velocity ($v(t)\sim t^{-\gamma}$). To a good accuracy our results confirm the scaling relation $\xi + \gamma =1$. In the two-dimensional case our results are in a good agreement with those obtained from the Boltzmann kinetic theory.

We investigate the kinetics of $A+B \to 0$ reaction with the local attractive interaction between opposite species in one spatial dimension. The attractive interaction leads to isotropic diffusions inside segregated single species domains, and accelerates the reactions of opposite species at the domain boundaries. At equal initial densities of $A$ and $B$, we analytically and numerically show that the density of particles ($\rho$), the size of domains ($\ell$), the distance b...

A simple example of a non-equilibrium system for which fluctuations are important is a system of particles which diffuse and may annihilate in pairs on contact. The renormalization group can be used to calculate the time dependence of the density of particles, and provides both an exact value for the exponent governing the decay of particles and an epsilon-expansion for the amplitude of this power law. When the diffusion is anomalous, as when the particles perform Levy flight...

We study the pairwise annihilation process $A+A\to$ inert of a number of random walkers, which originally are localized in a small region in space. The size of the colony and the typical distance between particles increases with time and, consequently, the reaction rate goes down. In the long time limit the spatial density profile becomes scale invariant. The mean-field approximation of this scenario bears some surprises. It predicts an upper critical dimension $d_c=2$, with ...

We consider the reaction zone that grows between separated regions of diffusing species $A$ and $B$ that react according to $mA+nB\to 0$, within the framework of the mean-fieldlike reaction-diffusion equations. For distances from the centre of the reaction zone much smaller than the diffusion length $X_D\equiv \sqrt{Dt}$, the particle density profiles are described by the scaling forms predicted by a quasistatic approximation, whereas they have a diffusive cutoff at a distanc...

We propose a model for diffusion-limited annihilation of two species, $A+B\to A$ or $B$, where the motion of the particles is subject to a drift. For equal initial concentrations of the two species, the density follows a power-law decay for large times. However, the decay exponent varies continuously as a function of the probability of which particle, the hopping one or the target, survives in the reaction. These results suggest that diffusion-limited reactions subject to dri...