Depletion driven adsorption of colloidal rods onto a hard wall

We elucidate the molecular forces leading to assembly of two dimensional membrane-like structures composed of a one rod-length thick monolayer of aligned rods from an immiscible suspension of hard rods and depleting polymers. We perform simulations which predict that monolayer membranes are thermodynamically stable above a critical rod aspect ratio and below a critical depletion interaction length scale. Outside of these conditions alternative structures such as stacked smect...

The surface tension, the adsorption, and the depletion thickness of polymers close to a single nonadsorbing colloidal sphere are computed by means of Monte Carlo simulations. We consider polymers under good-solvent conditions and in the thermal crossover region between good-solvent and $\theta$ behavior. In the dilute regime we consider a wide range of values of $q$, from $q = 0$ (planar surface) up to $q\approx 30$-50, while in the semidilute regime, for $\rho_p/\rho_p^*\le ...

The subject of this work is the adsorption transition of a long flexible self-avoiding polymer chain onto a rigid thin rod. The rod is represented by a cylinder of radius R with a short-ranged attractive surface potential for the chain monomers. General scaling results are obtained by using renormalization group arguments in conjunction with available results for quantum field theories with curved boundaries [McAvity and Osborn 1993 Nucl. Phys. B 394, 728]. Relevant critical ...

Using numerical simulations, we study how a solution of small active disks, acting as depletants, induces effective interactions on large passive colloids. Specifically, we analyze how the range, strength, and sign of these interactions are crucially dependent on the shape of the colloids. Our findings indicate that while colloidal rods experience a long-ranged predominantly attractive interaction, colloidal disks feel a purely repulsive force that is short-ranged in nature a...

We present particulate simulation results for translational and rotational friction components of a shish-kebab model of a colloidal rod with aspect ratio (length over diameter) $L/D = 10$ in the presence of a planar hard wall. Hydrodynamic interactions between rod and wall cause an overall enhancement of the friction tensor components. We find that the friction enhancements to reasonable approximation scale inversely linear with the closest distance $d$ between the rod surfa...

Polymer adsorption is a fundamental problem in statistical mechanics that has direct relevance to diverse disciplines ranging from biological lubrication to stability of colloidal suspensions. We combine experiments with computer simulations to investigate depletion induced adsorption of semi-flexible polymers onto a hard-wall. Three dimensional filament configurations of partially adsorbed F-actin polymers are visualized with total internal reflection fluorescence microscopy...

Interfacial properties of colloid--polymer mixtures are examined within an effective one--component representation, where the polymer degrees of freedom are traced out, leaving a fluid of colloidal particles interacting via polymer--induced depletion forces. Restriction is made to zero, one and two--body effective potentials, and a free energy functional is used which treats colloid excluded volume correlations within Rosenfeld's Fundamental Measure Theory, and depletion--ind...

The depletion interaction between two parallel repulsive walls confining a dilute solution of long and flexible polymer chains is studied by field-theoretic methods. Special attention is paid to self-avoidance between chain monomers relevant for polymers in a good solvent. Our direct approach avoids the mapping of the actual polymer chains on effective hard or soft spheres. We compare our results with recent Monte Carlo simulations [A. Milchev and K. Binder, Eur. Phys. J. B 3...

We study the behavior of self-propelled nano- and micro-rods in three dimensions, confined between two parallel walls, by simulations and scaling arguments. Our simulations include thermal fluctuations and hydrodynamic interactions, which are both relevant for the dynamical behavior at nano- to micrometer length scales. In order to investigate the importance hydrodynamic interactions, we also perform Brownian-dynamics-like simulations. In both cases, we find that self-propell...

The behavior of mesoscopic particles dissolved in a dilute solution of long, flexible, and nonadsorbing polymer chains is studied by field-theoretic methods. For spherical and cylindrical particles the solvation free energy for immersing a single particle in the solution is calculated explicitly. Important features are qualitatively different for self-avoiding polymer chains as compared with ideal chains. The results corroborate the validity of the Helfrich-type curvature exp...