Derivation and Improvements of the Quantum Canonical Ensemble from a Regularized Microcanonical Ensemble

Typically, in order to obtain finite-size scaling laws for quantities in the microcanonical ensemble, an assumption is taken as a starting point. In this paper, consistency of such a Microcanonical Finite-Size Scaling Assumption with its commonly accepted canonical counterpart is shown, which puts Microcanonical Finite-Size Scaling on a firmer footing.

Boltzmann's principle is used to select the "most probable" realization (macrostate) of an isolated or closed thermodynamic system, containing a small number of particles ($N \llsp \infty$), for both classical and quantum statistics. The inferred probability distributions provide the means to define intensive variables and construct thermodynamic relationships for small microcanonical systems, which do not satisfy the thermodynamic limit. This is of critical importance to nan...

We derive a lattice approximation for a class of equilibrium quantum statistics describing the behaviour of any combination and number of bosonic and fermionic particles with any sufficiently binding potential. We then develop an intuitive Monte Carlo algorithm which can be used for the computation of expectation values in canonical and Gaussian ensembles and give lattice observables which will converge to the energy moments in the continuum limit. The focus of the discussion...

We develop a method using a coarse graining of the energy fluctuations of an equilibrium quantum system which produces simple parameterizations for the behaviour of the system. As an application, we use these methods to gain more understanding on the standard Boltzmann-Gibbs statistics and on the recently developed Tsallis statistics. We conclude on a discussion of the role of entropy and the maximum entropy principle in thermodynamics.

We present a quantum algorithm for the microcanonical thermal pure quantum (TPQ) method, which has an advantage in evaluating thermodynamic quantities at finite temperatures, by combining with some recently developed techniques derived from quantum singular value transformation. When the ground energy of quantum systems has already been obtained precisely, the multiple products of the Hamiltonian are efficiently realized and the TPQ states at low temperatures are systematical...

In this paper, we consider the volume enclosed by the microcanonical ensemble in phase space as a statistical ensemble. This can be interpreted as an intermediate image between the microcanonical and the canonical pictures. By maintaining the ergodic hypothesis over this ensemble, that is, the equiprobability of all its accessible states, the equivalence of this ensemble in the thermodynamic limit with the microcanonical and the canonical ensembles is suggested by means of ge...

The phase space of quantum mechanics can be viewed as the complex projective space endowed with a Kaehlerian structure given by the Fubini-Study metric and an associated symplectic form. We can then interpret the Schrodinger equation as generating a Hamiltonian dynamics. Based upon the geometric structure of the quantum phase space we introduce the corresponding natural microcanonical and canonical ensembles. The resulting density matrix for the canonical ensemble differs fro...

A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The distinguishing feature of the proposed equilibrium state is that the corresponding density of states is a continuous function of the energy, and hence thermodynamic functions are well defined for finite quantum systems. The density of states, how...

We define a natural coarse-graining procedure which can be applied to any closed equilibrium quantum system described by a density matrix ensemble and we show how the coarse-graining leads to the Gaussian and canonical ensembles. After this motivation, we present two ways of evaluating the Gaussian expectation values with lattice simulations. The first one is computationally demanding but general, whereas the second employs only canonical expectation values but it is applicab...

We numerically investigate quantum quenches of a nonintegrable hard-core Bose-Hubbard model to test the accuracy of the microcanonical ensemble in small isolated quantum systems. We show that, in a certain range of system size, the accuracy increases with the dimension of the Hilbert space $D$ as $1/D$. We ascribe this rapid improvement to the absence of correlations between many-body energy eigenstates as well as to the eigenstate thermalization. Outside of that range, the a...