The Feynman effective classical potential in the Schr\"odinger formulation

We present an analysis of the Feynman path centroid density that provides new insight into the correspondence between the path integral and the Schr\"odinger formulations of statistical mechanics. The path centroid density is a central concept for several approximations (centroid molecular dynamics, quantum transition state theory, and pure quantum self-consistent harmonic approximation) that are used in path integral studies of thermodynamic and dynamical properties of quant...

We comment on the paper "Feynman Effective Classical Potential in the Schrodinger Formulation"[Phys. Rev. Lett. 81, 3303 (1998)]. We show that the results in this paper about the time evolution of a wave packet in a double well potential can be properly explained by resorting to a variational principle for the effective action. A way to improve on these results is also discussed.

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The Feynman path integral representation of quantum theory is used in a non--parametric Bayesian approach to determine quantum potentials from measurements on a canonical ensemble. This representation allows to study explicitly the classical and semiclassical limits and provides a unified description in terms of functional integrals: the Feynman path integral for the statistical operator, and the integration over the space of potentials for calculating the predictive density....

Work statistics characterizes important features of a non-equilibrium thermodynamic process. But the calculation of the work statistics in an arbitrary non-equilibrium process is usually a cumbersome task. In this work, we study the work statistics in quantum systems by employing Feynman's path-integral approach. We derive the analytical work distributions of two prototype quantum systems. The results are proved to be equivalent to the results obtained based on Schr\"{o}dinge...

In this paper we show how Feynman diagrams, which are used as a tool to implement perturbation theory in quantum field theory, can be very useful also in classical mechanics, provided we introduce also at the classical level concepts like path integrals and generating functionals.

It is shown how the time-dependent Schr\"{o}dinger equation may be simply derived from the dynamical postulate of Feynman's path integral formulation of quantum mechanics and the Hamilton-Jacobi equation of classical mechanics. Schr\"{o}dinger's own published derivations of quantum wave equations, the first of which was also based on the Hamilton-Jacobi equation, are also reviewed. The derivation of the time-dependent equation is based on an {\it a priori} assumption equivale...

Feynman and Hibbs were the first to variationally determine an effective potential whose associated classical canonical ensemble approximates the exact quantum partition function. We examine the existence of a map between the local potential and an effective classical potential which matches the exact quantum equilibrium density and partition function. The usefulness of such a mapping rests in its ability to readily improve Born-Oppenheimer potentials for use with classical s...

We derive two path integral estimators for the derivative of the quantum mechanical potential of mean force (PMF), which may be numerically integrated to yield the PMF. For the first estimator, we perform the differentiation on the exact path integral, and for the second, we perform the differentiation on the path integral after discretization. These estimators are successfully validated against reference results for the harmonic oscillator and Lennard-Jones dimer systems usi...

In the framework of non-relativistic QED, we show that the renormalized mass of the electron (after having taken into account radiative corrections) appears as the kinematic mass in its response to an external potential force. Specifically, we study the dynamics of an electron in a slowly varying external potential and with slowly varying initial conditions and prove that, for a long time, it is accurately described by an associated effective dynamics of a Schr\"odinger elect...