October 5, 2004
Solutions obtained by the quasilinearization method (QLM) are compared with the WKB solutions. While the WKB method generates an expansion in powers of h, the quasilinearization method (QLM) approaches the solution of the nonlinear equation obtained by casting the Schroedinger equation into the Riccati form by approximating nonlinear terms by a sequence of linear ones. It does not rely on the existence of any kind of smallness parameter. It also, unlike the WKB, displays no unphysical turning point singularities. It is shown that both energies and wave functions obtained in the first QLM iteration are accurate to a few parts of the percent. Since the first QLM iterate is represented by the closed expression it allows to estimate analytically and precisely the role of different parameters, and influence of their variation on the properties of the quantum systems. The next iterates display very fast quadratic convergence so that accuracy of energies and wave functions obtained after a few iterations is extremely high, reaching 20 significant figures for the energy of the sixth iterate. It is therefore demonstrated that the QLM method could be preferable over the usual WKB method.
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The quasilinearization method (QLM) of solving nonlinear differential equations is applied to the quantum mechanics by casting the Schr\"{o}dinger equation in the nonlinear Riccati form. The method, whose mathematical basis in physics was discussed recently by one of the present authors (VBM), approaches the solution of a nonlinear differential equation by approximating the nonlinear terms by a sequence of the linear ones, and is not based on the existence of some kind of a s...
June 14, 2004
Solutions obtained by the quasilinearization method (QLM) are compared with the WKB solutions. Expansion of the $p$-th QLM iterate in powers of $\hbar$ reproduces the structure of the WKB series generating an infinite number of the WKB terms with the first $2^p$ terms reproduced exactly. The QLM quantization condition leads to exact energies for the P\"{o}schl-Teller, Hulthen, Hylleraas, Morse, Eckart potentials etc. For other, more complicated potentials the first QLM iterat...
September 21, 2004
It is shown that the quasilinearization method (QLM) sums the WKB series. The method approaches solution of the Riccati equation (obtained by casting the Schr\"{o}dinger equation in a nonlinear form) by approximating the nonlinear terms by a sequence of the linear ones, and is not based on the existence of a smallness parameter. Each p-th QLM iterate is expressible in a closed integral form. Its expansion in powers of $\hbar$ reproduces the structure of the WKB series generat...
March 21, 2006
Ground state energies and wave functions of quartic and pure quartic oscillators are calculated by first casting the Schr\"{o}dinger equation into a nonlinear Riccati form and then solving that nonlinear equation analytically in the first iteration of the quasilinearization method (QLM). In the QLM the nonlinear differential equation is solved by approximating the nonlinear terms by a sequence of linear expressions. The QLM is iterative but not perturbative and gives stable s...
October 26, 2007
High-precision approximate analytic expressions for energies and wave functions are found for arbitrary physical potentials. The Schr\"{o}dinger equation is cast into nonlinear Riccati equation, which is solved analytically in first iteration of the quasi-linearization method (QLM). The zeroth iteration is based on general features of the exact solution near the boundaries. The approach is illustrated on the Yukawa potential. The results enable accurate analytical estimates o...
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We analyze quantitatively the accuracy of eigenfunction and eigenvalue calculations in the frame work of WKB and instanton semiclassical methods. We show that to estimate the accuracy it is enough to compare two linearly independent (with the same quantum number) solutions to the Schr\"odinger equations with the potential under study, and with the approximating piecewise smooth potential. The main advantage of the approach is related to the appropriate choice of the approxima...
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