The Physical Basis of the Gibbs-von Neumann entropy

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space accessible to an isolated system [1]. There is no quantum mechanical analog to this. Instead, Von Neumann's hypothesis for the entropy [2] is most widely used. However this gives zero for systems with a known wave function, that is a pure sta...

The paper deals with the generalization of both Boltzmann entropy and distribution in the light of most-probable interpretation of statistical equilibrium. The statistical analysis of the generalized entropy and distribution leads to some new interesting results of significant physical importance.

This paper is an introduction to the von Neumann entropy in a historic approach. Von Neumann's gedanken experiment is repeated, which led him to the formula of thermodynamic entropy of a statistical operator. In the analysis of his ideas we stress the role of superselection sectors and summarize von Neumann's knowledge about quantum mechanical entropy. The final part of the paper is devoted to important developments discovered long after von Neumann's work. Subadditivity and ...

We propose a generalisation of Gibbs' statistical mechanics into the domain of non-negligible phase space correlations. Derived are the probability distribution and entropy as a generalised ensemble average, replacing Gibbs-Boltzmann-Shannon's entropy definition enabling construction of new forms of statistical mechanics. The general entropy may also be of importance in information theory and data analysis. Application to generalised Lorentzian phase space elements yields the...

Entropy is one of the most basic concepts in thermodynamics and statistical mechanics. The most widely used definition of statistical mechanical entropy for a quantum system is introduced by von Neumann. While in classical systems, the statistical mechanical entropy is defined by Gibbs. The relation between these two definitions of entropy is still not fully explored. In this work, we study this problem by employing the phase-space formulation of quantum mechanics. For those ...

Depending on the exact experimental conditions, the thermodynamic properties of physical systems can be related to one or more thermostatistical ensembles. Here, we survey the notion of thermodynamic temperature in different statistical ensembles, focusing in particular on subtleties that arise when ensembles become non-equivalent. The 'mother' of all ensembles, the microcanonical ensemble, uses entropy and internal energy (the most fundamental, dynamically conserved quantity...

Attempts to establish microcanonical entropy as an adiabatic invariant date back to works of Gibbs and Hertz. More recently, a consistency relation based on adiabatic invariance has been used to argue for the validity of Gibbs (volume) entropy over Boltzmann (surface) entropy. Such consistency relation equates derivatives of thermodynamic entropy to ensemble average of the corresponding quantity in micro-state space (phase space or Hilbert space). In this work we propose to r...

There are three levels of description in classical statistical mechanics, the microscopic/dynamic, the macroscopic/statistical and the thermodynamic. At one end there is a well-used concept of equilibrium in thermodynamics and at the other dynamic equilibrium does not exist in measure-preserving reversible dynamic systems. Statistical mechanics attempts to situate equilibrium at the macroscopic level in the Boltzmann approach and at the statistical level in the Gibbs approach...

For more than 100 years, one of the central concepts in statistical mechanics has been the microcanonical ensemble, which provides a way of calculating the thermodynamic entropy for a specified energy. A controversy has recently emerged between two distinct definitions of the entropy based on the microcanonical ensemble: (1) The Boltzmann entropy, defined by the density of states at a specified energy, and (2) The Gibbs entropy, defined by the sum or integral of the density o...

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the N-body phase space with the given total energy. Due to Boltzmann-Planck's principle, e^S=tr(\delta(E-H)), its geometrical size is related to the entropy S(E,N,V,...). This definition does not invoke any information theory, no thermodynamic limit, no extensivity, and no homogeneity assumption. Therefore, it describes the equ...