One-shot information-theoretical approaches to fluctuation theorems

Two approaches to small-scale and quantum thermodynamics are fluctuation relations and one-shot statistical mechanics. Fluctuation relations (such as Crooks' Theorem and Jarzynski's Equality) relate nonequilibrium behaviors to equilibrium quantities such as free energy. One-shot statistical mechanics involves statements about every run of an experiment, not just about averages over trials. We investigate the relation between the two approaches. We show that both approaches ...

Thermodynamics describes large-scale, slowly evolving systems. Two modern approaches generalize thermodynamics: fluctuation theorems, which concern finite-time nonequilibrium processes, and one-shot statistical mechanics, which concerns small scales and finite numbers of trials. Combining these approaches, we calculate a one-shot analog of the average dissipated work defined in fluctuation contexts: the cost of performing a protocol in finite time instead of quasistatically. ...

This topical review article gives an overview of the interplay between quantum information theory and thermodynamics of quantum systems. We focus on several trending topics including the foundations of statistical mechanics, resource theories, entanglement in thermodynamic settings, fluctuation theorems and thermal machines. This is not a comprehensive review of the diverse field of quantum thermodynamics; rather, it is a convenient entry point for the thermo-curious informat...

What is the major difference between large and small systems? At small length-scales the dynamics is dominated by fluctuations, whereas at large scales fluctuations are irrelevant. Therefore, any thermodynamically consistent description of quantum systems necessitates a thorough understanding of the nature and consequences of fluctuations. In this chapter, we outline two closely related fields of research that are commonly considered separately -- fluctuation forces and fluct...

Conventional statistical mechanics describes large systems and averages over many particles or over many trials. But work, heat, and entropy impact the small scales that experimentalists can increasingly control, e.g., in single-molecule experiments. The statistical mechanics of small scales has been quantified with two toolkits developed in quantum information theory: resource theories and one-shot information theory. The field has boomed recently, but the theorems amassed h...

It will be shown, how the Boltzmannian ideas on statistical physics can be naturally applied to nonequilibrium thermodynamics. A similar approach for treating nonequilibrium phenomena has been successfully used by Einstein and Smoluchowski treating fluctuations. It will be argued, that due to the reversibility of the microscopic equations, all processes - also macroscopic ones - must at least in principle be reversible. Also, a clear conceptual distinction between equilibrium...

These lecture notes provide an elementary introduction, within the framework of finite quantum systems, to recent developments in the theory of entropic fluctuations.

The thermodynamics of quantum systems driven out of equilibrium has attracted increasing attention in last the decade, in connection with quantum information and statistical physics, and with a focus on non-classical signatures. While a first approach can deal with average thermodynamics quantities over ensembles, in order to establish the impact of quantum and environmental fluctuations during the evolution, a continuous quantum measurement of the open system is required. He...

The work content of non-equilibrium systems in relation to a heat bath is often analyzed in terms of expectation values of an underlying random work variable. However, we show that when optimizing the expectation value of the extracted work, the resulting extraction process is subject to intrinsic fluctuations, uniquely determined by the Hamiltonian and the initial distribution of the system. These fluctuations can be of the same order as the expected work content per se, in ...

There has been an increasing interest in the quantification of nearly deterministic work extraction from a finite number of copies of microscopic particles in finite time. This paradigm, so called single-shot epsilon-deterministic work extraction, considers processes with small failure probabilities. However, the resulting fluctuations in the extracted work entailed by this failure probability have not been studied before. In the standard thermodynamics paradigm fluctuation t...