One-shot information-theoretical approaches to fluctuation theorems

We consider stochastic thermodynamics as a theory of statistical inference for experimentally observed fluctuating time-series. To that end, we introduce a general framework for quantifying the knowledge about the dynamical state of the system on two scales: a fine-grained or microscopic, deterministic and a coarse-grained or mesoscopic, stochastic level of description. For a generic model dynamics, we show how the mathematical expressions for fluctuating entropy changes used...

Thermodynamics is based on the notions of energy and entropy. While energy is the elementary quantity governing physical dynamics, entropy is the fundamental concept in information theory. In this work, starting from first principles, we give a detailed didactic account on the relations between energy and entropy and thus physics and information theory. We show that thermodynamic process inequalities, like the Second Law, are equivalent to the requirement that an effective de...

Fluctuation theorems, which have been developed over the past 15 years, have resulted in fundamental breakthroughs in our understanding of how irreversibility emerges from reversible dynamics, and have provided new statistical mechanical relationships for free energy changes. They describe the statistical fluctuations in time-averaged properties of many-particle systems such as fluids driven to nonequilibrium states, and provide some of the very few analytical expressions tha...

This Colloquium is a fast journey through the build-up of key thermodynamical concepts, i.e. work, heat and irreversibility -- and how they relate to information. Born at the time of industrial revolution to optimize the exploitation of thermal resources, these concepts have been adapted to small systems where thermal fluctuations are predominant. Extending the framework to quantum fluctuations is a great challenge of quantum thermodynamics, that opens exciting research lines...

Classical thermodynamics is unrivalled in its range of applications and relevance to everyday life. It enables a description of complex systems, made up of microscopic particles, in terms of a small number of macroscopic quantities, such as work and entropy. As systems get ever smaller, fluctuations of these quantities become increasingly relevant, prompting the development of stochastic thermodynamics. Recently we have seen a surge of interest in exploring the quantum regime...

Recent advances in experimental techniques allow one to measure and control systems at the level of single molecules and atoms. Here gaining information about fluctuating thermodynamic quantities is crucial for understanding nonequilibrium thermodynamic behavior of small systems. To achieve this aim, stochastic thermodynamics offers a theoretical framework, and nonequilibrium equalities such as Jarzynski equality and fluctuation theorems provide key information about the fluc...

We establish the fluctuation theorem in the presence of information exchange between a nonequilibrium system and other degrees of freedom such as an observer and a feedback controller, where the amount of information exchange is added to the entropy production. The resulting generalized second law sets the fundamental limit of energy dissipation and energy cost during the information exchange. Our results apply not only to feedback-controlled processes but also to a much broa...

The second law of classical thermodynamics, based on the positivity of the entropy production, only holds for deterministic processes. Therefore the Second Law in stochastic quantum thermodynamics may not hold. By making a fundamental connection between thermodynamics and information theory we will introduce a new way of defining the Second Law which holds for both deterministic classical and stochastic quantum thermodynamics. Our work incorporates information well into the S...

In the standard framework of thermodynamics the work produced or consumed in a process is a random variable whose average value is bounded by the change in the free energy of the system. This work is calculated without regard for the size of its fluctuations. We find that in some processes, such as reversible cooling, the fluctuations of the work can diverge. Small or fragile thermal machines may be unable to cope with large fluctuations. Hence, with the present focus on nano...

This article sets up a formalism to describe stochastic thermodynamics for driven out-of-equilibrium open quantum systems. A stochastic Schr\"odinger equation allows to construct quantum trajectories describing the dynamics of the system state vector in presence of an eventually monitored environment. Thermodynamic quantities are defined at the single quantum trajectory level, independently of any energy measurement, at any time of the protocol. We thereby identify coherent c...