October 4, 2004
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June 24, 2007
We show that the principle of entropy increase may be exactly founded on a few axioms valid not only for quantum and classical statistics, but also for a wide range of statistical processes.
December 8, 2015
The maximum entropy principle (MEP) apparently allows us to derive, or justify, fundamental results of equilibrium statistical mechanics. Because of this, a school of thought considers the MEP as a powerful and elegant way to make predictions in physics and other disciplines, which constitutes an alternative and more general method than the traditional ones of statistical mechanics. Actually, careful inspection shows that such a success is due to a series of fortunate facts t...
September 26, 2019
The mechanism by which thermodynamics sets the direction of time's arrow has long fascinated scientists. Here, we show that a machine learning algorithm can learn to discern the direction of time's arrow when provided with a system's microscopic trajectory as input. The performance of our algorithm matches fundamental bounds predicted by nonequilibrium statistical mechanics. Examination of the algorithm's decision-making process reveals that it discovers the underlying thermo...
July 17, 2014
We take up the question why the initial entropy in the universe was small, in the context of evolution of the entropy of a classical system. We note that coarse-graining is a an important aspect of entropy evaluation which can reverse the direction of the increase in entropy, i.e., the direction of thermodynamic arrow of time. Then we investigate the role of decoherence in the selection of coarse-graining and explain how to compute entropy for a decohered classical system. Fi...
March 6, 2006
What is the best description that we can construct of a thermodynamic system that is not in equilibrium, given only one, or a few, extra parameters over and above those needed for a description of the same system at equilibrium? Here, we argue the most appropriate additional parameter is the non-equilibrium entropy of the system, and that we should not attempt to estimate the probability distribution of the system, but rather the metaprobability (or hyperensemble) that the sy...
October 23, 2023
Although information theory resolves inconsistencies (known under the form of famous enigmas) of the traditional approach of thermostatistics, its place in the corresponding literature is not what it deserves. This article supports the idea that this is mainly due to epistemological rather than scientific reasons: the subjectivity introduced into physics is perceived as a problem. Here is an attempt to expose and clarify where exactly this subjectivity lies: in the representa...
April 9, 2022
Even today, the concept of entropy is perceived by many as quite obscure. The main difficulty is analyzed as being fundamentally due to the subjectivity and anthropocentrism of the concept that prevent us to have a sufficient distance to embrace it. However, it is pointed out that the lack of coherence of certain presentations or certain preconceived ideas do not help. They are of three kinds : 1) axiomatic thermodynamics; 2) inconsistent solutions of certain paradoxes; 3) re...
October 1, 2014
The present paper is meant to give a simple introduction to the problem of the connection between microscopic dynamics and statistical laws. For sake of simplicity, we mostly refer to non-dissipative dynamics, since dissipation adds technical difficulties to the conceptual issues, although part of our discussion extends beyond this limit. In particular, the relevance of chaos and ergodicity is here confronted with that of the large number of degrees of freedom. In Section 2, ...
February 4, 2008
The arrow of time dilemma: the laws of physics are invariant for time inversion, whereas the familiar phenomena we see everyday are not (i.e. entropy increases). I show that, within a quantum mechanical framework, all phenomena which leave a trail of information behind (and hence can be studied by physics) are those where entropy necessarily increases or remains constant. All phenomena where the entropy decreases must not leave any information of their having happened. This s...
April 22, 2021
Through extended consideration of two wide classes of case studies -- dilute gases and linear systems -- I explore the ways in which assumptions of probability and irreversibility occur in contemporary statistical mechanics, where the latter is understood as primarily concerned with the derivation of quantitative higher-level equations of motion, and only derivatively with underpinning the equilibrium concept in thermodynamics. I argue that at least in this wide class of exam...