The Kondo Resonance in Electron Spectroscopy

Recent experiments have suggested that the electron-phonon coupling may play an important role in the $\gamma \rightarrow \alpha$ volume collapse transition in Cerium. A minimal model for the description of such transition is the periodic Anderson model. In order to better understand the effect of the electron-phonon interaction on the volume collapse transition, we study the periodic Anderson model with coupling between Holstein phonons and electrons in the conduction band. ...

We present numerically exact predictions of the periodic and single-impurity Anderson models to address photoemission experiments on heavy Fermion systems. Unlike the single impurity model the lattice model is able to account for the enhanced intensity, dispersion, and apparent weak temperature dependence of the Kondo resonant peak seen in recent controversial photoemission experiments. We present a consistent interpretation of these results as a crossover from the impurity r...

Band calculations for Ce compounds with the AuCu$_{3}$-type crystal structure were carried out on the basis of dynamical mean field theory (DMFT). The results of applying the calculation to CeIn$_{3}$ and CeSn$_{3}$ are presented as the second in a series of papers. The Kondo temperature and crystal-field splitting are obtained, respectively, as 190 and 390 K (CeSn$_{3}$), 8 and 160 K (CeIn$_{3}$ under ambient pressure), and 30 and 240 K (CeIn$_{3}$ at a pressure of 2.75 GPa)...

We present high-resolution angle-resolved photoemission spectroscopy studies of trivalent CeB6 and divalent BaB6 rare-earth hexaborides. We find that the Fermi surface electronic structure of CeB6 consists of large oval-shape pockets around the X points of the Brillouin zone, while the states around the zone centre 'Gamma' point are strongly renormalized. Our first-principles calculations agree with data around the X points, but not at the 'Gamma' points, indicating areas of ...

We investigate the electronic structure of a novel Kondo lattice system CeCuX2 (X = As/Sb) employing high resolution depth-resolved photoemission spectroscopy of high quality single crystalline materials. CeCuSb2 and CeCuAs2 represent different regimes of the Doniach phase diagram exhibiting Kondo-like transport properties and CeCuSb2 is antiferromagnetic (TN ~ 6.9 K) while CeCuAs$_2$ does not show long-range magnetic order down to the lowest temperature studied. In this stud...

Heavy-fermion or Kondo lattice materials are considered to be typical strongly correlated systems, for which mean-field approximations have shown that the Coulomb interaction increases the effective mass and narrows the band gap. In this paper, to clarify interaction effects on the electronic excitation, the spectral function of the Kondo lattice and periodic Anderson models is studied around Kondo insulators in the strong-coupling regime, by using the non-Abelian dynamical d...

Cerium (Ce)-based heavy-fermion materials have a characteristic double-peak structure (mid-IR peak) in the optical conductivity [$\sigma(\omega)$] spectra originating from the strong conduction ($c$)--$f$ electron hybridization. To clarify the behavior of the mid-IR peak at a low $c$-$f$ hybridization strength, we compared the $\sigma(\omega)$ spectra of the isostructural antiferromagnetic and heavy-fermion Ce compounds with the calculated unoccupied density of states and the...

The electronic structure of the Cr(001) surface with its sharp resonance at the Fermi level is a subject of controversial debate of many experimental and theoretical works. To date, it is unclear whether the origin of this resonance is an orbital Kondo or an electron-phonon coupling effect. We have combined ab initio density functional calculations with dynamical mean-field simulations to calculate the orbitally resolved spectral function of the Cr(001) surface. The calculate...

Many heavy fermion materials are known to crossover from the Kondo lattice regime to the mixed-valent regime or vice-versa as a function of pressure or doping. We study this crossover theoretically by employing the periodic Anderson model within the framework of the dynamical mean field theory. Changes occurring in the dynamics and transport across this crossover are highlighted. As the valence is decreased (increased) relative to the Kondo lattice regime, the Kondo resonance...

We study the electronic structure of a Pauli paramagnetic compound, La(2)CoSi(3) using photoemission spectroscopy and ab initio band structure calculations. Experimental valence band spectra exhibit signature of electron correlation induced feature around 2.5 eV - the correlation strength among Co 3d electrons is estimated to be close to 3 eV. The Co 2p core level spectra also exhibit correlation induced satellite features consistent with the scenario in the valence band spec...