ID: cond-mat/0609149

Studies on the Weak Itinerant Ferromagnet SrRuO3 under High Pressure to 34 GPa

September 6, 2006

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J. J. Hamlin, S. Deemyad, J. S. Schilling, M. K. Jacobsen, R. S. Kumar, A. L. Cornelius, G. Cao, J. J. Neumeier
Condensed Matter
Strongly Correlated Electron...

The dependence of the Curie temperature Tc on nearly hydrostatic pressure has been determined to 17.2 GPa for the weak itinerant ferromagnetic SrRuO3 in both polycrystalline and single-crystalline form. Tc is found to decrease under pressure from 162 K to 42.7 K at 17.2 GPa in nearly linear fashion at the rate dTc/dP = -6.8 K/GPa. No superconductivity was found above 4 K in the pressure range 17 to 34 GPa. Room-temperature X-ray diffraction studies to 25.3 GPa reveal no structural phase transition but indicate that the average Ru-O-Ru bond angle passes through a minimum near 15 GPa. The bulk modulus and its pressure derivative were determined to be B =192(3) GPa and B' = 5.0(3), respectively. Parallel ac susceptibility studies on polycrystalline CaRuO3 at 6 and 8 GPa pressure found no evidence for either ferromagnetism or superconductivity above 4 K.

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