Anisotropic Diffusion-Limited Reactions with Coagulation and Annihilation

The one-dimensional reaction diffusion process AA->A and A0A->AAA is exactly solvable through the empty interval method if the diffusion rate equals the coagulation rate. Independently of the particle production rate, the model is always in the universality class of diffusion-annihilation. This allows us to check analytically the universality of finite-size scaling in a non-equilibrium critical point.

We present a mean field model for coagulation ($A+A\to A$) and annihilation ($A+A\to 0$) reactions on lattices of traps with a distribution of depths reflected in a distribution of mean escape times. The escape time from each trap is exponentially distributed about the mean for that trap, and the distribution of mean escape times is a power law. Even in the absence of reactions, the distribution of particles over sites changes with time as particles are caught in ever deeper ...

We consider the trapping reaction A + B -> B in space dimension d<=2. By formally eliminating the B particles from the problem we derive an effective dynamics for the A particles from which the survival probability of a given A particle and the statistics of its spatial fluctuations can be calculated in a rather general way. The method can be extended to the study of annihilation/coalescence reactions, B + B -> 0 or B, in d=2.

The reaction process $A+B->C$ is modelled for ballistic reactants on an infinite line with particle velocities $v_A=c$ and $v_B=-c$ and initially segregated conditions, i.e. all A particles to the left and all B particles to the right of the origin. Previous, models of ballistic annihilation have particles that always react on contact, i.e. pair-reaction probability $p=1$. The evolution of such systems are wholly determined by the initial distribution of particles and therefo...

We describe the spatial structure of particles in the (one dimensional) two-species annihilation reaction A + B --> 0, where both species have a uniform drift in the same direction and like species have a hard core exclusion. For the case of equal initial concentration, at long times, there are three relevant length scales: the typical distance between similar (neighboring) particles, the typical distance between dissimilar (neighboring) particles, and the typical size of a c...

In reaction-diffusion models of annihilation reactions in low dimensions, single-particle dynamics provides a bottleneck for reactions, leading to an anomalously slow approach to the empty state. Here, we construct a reaction model with a reciprocal bottleneck on particle dynamics where single-particle motion conserves the center of mass. We show that such a constrained reaction-diffusion dynamics does not approach an empty state but freezes at late times in a state with frag...

The dynamics of a coupled two-component nonequilibrium system is examined by means of continuum field theory representing the corresponding master equation. Particles of species A may perform hopping processes only when particles of different type B are present in their environment. Species B is subject to diffusion-limited reactions. If the density of B particles attains a finite asymptotic value (active state), the A species displays normal diffusion. On the other hand, if ...

The persistence properties of a set of random walkers obeying the A+B -> 0 reaction, with equal initial density of particles and homogeneous initial conditions, is studied using two definitions of persistence. The probability, P(t), that an annihilation process has not occurred at a given site has the asymptotic form $P(t) -> const + t^{-\theta}$, where $\theta$ is the persistence exponent (``type I persistence''). We argue that, for a density of particles $\rho >> 1$, this n...

We present results of computer simulations of the diffusion-limited reaction process A+B->0, on the line, under extreme drift conditions, for lattices of up to 2^{27} sites, and where the process proceeds to completion (no particles left). These enormous simulations are made possible by the renormalized reaction-cell method (RRC). Our results allow us to resolve an existing controversy about the rate of growth of domain sizes, and about corrections to scaling of the concentra...

We study diffusion-limited pair annihilation $A+A\to 0$ on one-dimensional lattices with inhomogeneous nearest neighbour hopping in the limit of infinite reaction rate. We obtain a simple exact expression for the particle concentration $\rho_k(t)$ of the many-particle system in terms of the conditional probabilities $P(m;t|l;0)$ for a single random walker in a dual medium. For some disordered systems with an initially randomly filled lattice this leads asymptotically to $\bar...