Anisotropic Diffusion-Limited Reactions with Coagulation and Annihilation

We introduce a method of intervals for the analysis of diffusion-limited annihilation, A+A -> 0, on the line. The method leads to manageable diffusion equations whose interpretation is intuitively clear. As an example, we treat the following cases: (a) annihilation in the infinite line and in infinite (discrete) chains; (b) annihilation with input of single particles, adjacent particle pairs, and particle pairs separated by a given distance; (c) annihilation, A+A -> 0, along ...

A family of diffusion-annihilation processes is introduced, which is exactly solvable. This family contains parameters that control the diffusion- and annihilation- rates. The solution is based on the Bethe ansatz and using special boundary conditions to represent the reaction. The processes are investigated, both on the lattice and on the continuum. Special cases of this family of processes are the simple exclusion process and the drop-push model.

Diffusion-limited annihilation, $A+A\to 0$, and coalescence, $A+A\to A$, may both be exactly analyzed in one dimension. While the concentrations of $A$ particles in the two processes bear a simple relation, the inter-particle distribution functions (IPDF) exhibit remarkable differences. However, the IPDF is known exactly only for the coalescence process. We obtain the IPDF for the annihilation process, based on the Glauber spin approach and assuming that the IPDF's of nearest...

We present a detailed study of the effects of the initial distribution on the kinetic evolution of the irreversible reaction A+B -> 0 in one dimension. Our analytic as well as numerical work is based on a reaction-diffusion model of this reaction. We focus on the role of initial density fluctuations in the creation of the macroscopic patterns that lead to the well-known kinetic anomalies in this system. In particular, we discuss the role of the long wavelength components of t...

The $A + B\to 0$ diffusion-limited reaction, with equal initial densities $a(0) = b(0) = n_0$, is studied by means of a field-theoretic renormalization group formulation of the problem. For dimension $d > 2$ an effective theory is derived, from which the density and correlation functions can be calculated. We find the density decays in time as $a,b \sim C\sqrt{\D}(Dt)^{-d/4}$ for $d < 4$, with $\D = n_0-C^\prime n_0^{d/2} + \dots$, where $C$ is a universal constant, and $C^\p...

The finite-size scaling function and the leading corrections for the single species 1D coagulation model $(A + A \rightarrow A)$ and the annihilation model $(A + A \rightarrow \emptyset)$ are calculated. The scaling functions are universal and independent of the initial conditions but do depend on the boundary conditions. A similarity transformation between the two models is derived and used to connect the corresponding scaling functions.

Recently an exact solution has been found (M.Henkel and H.Hinrichsen, cond-mat/0010062) for the 1d coagulation production process: 2A ->A, A0A->3A with equal diffusion and coagulation rates. This model evolves into the inactive phase independently of the production rate with $t^{-1/2}$ density decay law. Here I show that cluster mean-field approximations and Monte Carlo simulations predict a continuous phase transition for higher diffusion/coagulation rates as considered in c...

Two-point density-density correlation functions for the diffusive binary reaction system $A+A\to\emptyset$ are obtained in one dimension via Monte Carlo simulation. The long-time behavior of these correlation functions clearly deviates from that of a recent analytical prediction of Bares and Mobilia [Phys. Rev. Lett. {\bf 83}, 5214 (1999)]. An alternative expression for the asymptotic behavior is conjectured from numerical data.

We study diffusion-limited coalescence, A+A<-->A$, in one dimension, and derive an exact solution for the steady state in the presence of a trap. Without the trap, the system arrives at an equilibrium state which satisfies detailed balance, and can therefore be analyzed by classical equilibrium methods. The trap introduces an irreversible element, and the stationary state is no longer an equilibrium state. The exact solution is compared to that of a reaction-diffusion equatio...

We consider a one-dimensional system with particles having either positive or negative velocity, which annihilate on contact. To the ballistic motion of the particle, a diffusion is superimposed. The annihilation may represent a reaction in which the two particles yield an inert species. This model has been the object of previous work, in which it was shown that the particle concentration decays faster than either the purely ballistic or the purely diffusive case. We report o...