Scaling Model of Annihilation-Diffusion Kinetics for Charged Particles with Long-Range Interactions

We consider the quantum reaction-diffusion dynamics in $d$ spatial dimensions of a Fermi gas subject to binary annihilation reactions $A+A \to \emptyset$. These systems display collective nonequilibrium long-time behavior, which is signalled by an algebraic decay of the particle density. Building on the Keldysh formalism, we devise a field theoretical approach for the reaction-limited regime, where annihilation reactions are scarce. By means of a perturbative expansion of the...

Using field-theoretic renormalization group methods the long-time behaviour of the A+B -> 0 annihilation reaction with equal initial densities n_A(0) = n_B(0) = n_0 in a quenched random velocity field is studied. At every point (x, y) of a d-dimensional system the velocity v is parallel or antiparallel to the x-axis and depends on the coordinates perpendicular to the flow. Assuming that v(y) have zero mean and short-range correlations in the y-direction we show that the densi...

The diffusion-controlled reaction $kA\rightarrow\emptyset$ is known to be strongly dependent on fluctuations in dimensions $d\le d_c=2/(k-1)$. We develop a field theoretic renormalization group approach to this system which allows explicit calculation of the observables as expansions in $\epsilon^{1/(k-1)}$, where $\epsilon=d_c-d$. For the density it is found that, asymptotically, $n\sim A_k t^{-d/2}$. The decay exponent is exact to all orders in $\epsilon$, and the amplitude...

We determine the evolving segregated or mixed morphology of charged-particle systems with long-range power-law interactions and overall charge neutrality that have been quenched to a low temperature. Segregated morphology systems are characterized by the size of uniformly charged domains, $L(t)$, the particle separation within the domains, $l_{AA}(t)$, the particle flux-density leaving the domains, $J(t)$, the width of reaction zones between domains, $W(t)$, the particle spac...

The $A + B\to 0$ diffusion-limited reaction, with equal initial densities $a(0) = b(0) = n_0$, is studied by means of a field-theoretic renormalization group formulation of the problem. For dimension $d > 2$ an effective theory is derived, from which the density and correlation functions can be calculated. We find the density decays in time as $a,b \sim C\sqrt{\D}(Dt)^{-d/4}$ for $d < 4$, with $\D = n_0-C^\prime n_0^{d/2} + \dots$, where $C$ is a universal constant, and $C^\p...

We study kinetics of single species reactions ("A+A -> 0") for general local reactivity Q and dynamical exponent z (rms displacement x_t ~ t^{1/z}.) For small molecules z=2, whilst z=4,8 for certain polymer systems. For dimensions d above the critical value d_c=z, kinetics are always mean field (MF). Below d_c, the density n_t initially follows MF decay, n_0 - n_t ~ n_0^2 Q t. A 2-body diffusion-controlled regime follows for strongly reactive systems (Q>Qstar ~ n_0^{(z-d)/d})...

The kinetics of the annihilation process, $A+A\to 0$, with ballistic particle motion is investigated when the distribution of particle velocities is {\it discrete}. This discreteness is the source of many intriguing phenomena. In the mean field limit, the densities of different velocity species decay in time with different power law rates for many initial conditions. For a one-dimensional symmetric system containing particles with velocity 0 and $\pm 1$, there is a particular...

We present a detailed analytical study of the $A+A\to\emptyset$ diffusion-annihilation process in complex networks. By means of microscopic arguments, we derive a set of rate equations for the density of $A$ particles in vertices of a given degree, valid for any generic degree distribution, and which we solve for uncorrelated networks. For homogeneous networks (with bounded fluctuations), we recover the standard mean-field solution, i.e. a particle density decreasing as the i...

We consider the dynamics of particles undergoing the reaction $A+A \to \emptyset$ in one dimension with a dynamic bias. Here the particles move towards their nearest neighbour with probability $0.5+\epsilon$ where $-0.5 \leq \epsilon < 0$. $\epsilon_c = -0.5$ is the deterministic limit where the nearest neighbour interaction is strictly repulsive. We show that the negative bias changes drastically the behaviour of the fraction of surviving particles $\rho(t)$ and persistence ...

Using the perturbative renormalization group, we study the influence of a random velocity field on the kinetics of the single-species annihilation reaction A+A->0 at and below its critical dimension d_c=2. We use the second-quantization formalism of Doi to bring the stochastic problem to a field-theoretic form. We investigate the reaction in the vicinity of the space dimension d=2 using a two-parameter expansion in $\epsilon$ and $\Delta$, where $\epsilon$ is the deviation fr...