September 12, 2012
The double well potential is arguably one of the most important potentials in quantum mechanics, because the solution contains the notion of a state as a linear superposition of `classical' states, a concept which has become very important in quantum information theory. It is therefore desirable to have solutions to simple double well potentials that are accessible to the undergraduate student. We describe a method for obtaining the numerically exact eigenenergies and eigenst...
November 27, 2017
The numerical version of the Hamilton-Jacobi quantization method, recently proposed, is applied to the one dimensional quartic oscillator. A suitable quantization condition is formulated and various energy levels and wave functions are computed. The results very well agree with those obtained by means of the Schroedinger equation, and confirm that the Quantum Hamilton Jacobi approach, which is the exact version of the semiclassical WKB scheme, is a self-contained quantization...
July 25, 2023
This paper presents a non-perturbative method for solving eigenproblems. This method applies to almost all potentials and provides non-perturbative approximations for any energy level. The method converts an eigenproblem into a perturbation problem, obtains perturbation solutions through standard perturbation theory, and then analytically continues the perturbative solution into a non-perturbative solution.
March 30, 2000
We obtain the rigorous WKB expansion to all orders for the radial Kepler problem, using the residue calculus in evaluating the WKB quantization condition in terms of a complex contour integral in the complexified coordinate plane. The procedure yields the exact energy spectrum of this Schr\"odinger eigenvalue problem and thus resolves the controversies around the so-called "Langer correction". The problem is nontrivial also because there are only a few systems for which all o...
August 15, 2022
Quantum mechanics has about a dozen exactly solvable potentials. Normally, the time-independent Schroedinger equation for them is solved by using a generalized series solution for the bound states (using the Froebenius method) and then an analytic continuation for the continuum states (if present). In this work, we present an alternative way to solve these problems, based on the Laplace method. This technique uses a similar procedure for the bound states and for the continuum...
January 24, 2002
We review an "exact semiclassical" resolution method for the general stationary 1D Schr\"odinger equation with a polynomial potential. This method avoids having to compute any Stokes phenomena directly; instead, it basically relies on an elementary Wronskian identity, and on a fully exact form of Bohr--Sommerfeld quantization conditions which can also be viewed as a Bethe-Ansatz system of equations that will "solve" the general polynomial 1D Schr\"odinger problem.
August 6, 2018
This paper is concerned with the efficient numerical computation of solutions to the 1D stationary Schr\"odinger equation in the semiclassical limit in the highly oscillatory regime. A previous approach to this problem based on explicitly incorporating the leading terms of the WKB approximation is enhanced in two ways: first a refined error analysis for the method is presented for a not explicitly known WKB phase, and secondly the phase and its derivatives will be computed wi...
November 13, 2004
In many physical problems it is not possible to find an exact solution. However, when some parameter in the problem is small, one can obtain an approximate solution by expanding in this parameter. This is the basis of perturbative methods, which have been applied and developed practically in all areas of Physics. Unfortunately many interesting problems in Physics are of non-perturbative nature and it is not possible to gain insight on these problems only on the basis of pertu...
February 9, 2016
We consider the time discretization based on Lie-Trotter splitting, for the nonlinear Schrodinger equation, in the semi-classical limit, with initial data under the form of WKB states. We show that both the exact and the numerical solutions keep a WKB structure, on a time interval independent of the Planck constant. We prove error estimates, which show that the quadratic observables can be computed with a time step independent of the Planck constant. The functional framework ...
November 26, 2001
The newly developed single trajectory quadrature method is applied to solve the ground state quantum wave function for Coulomb plus linear potential. The general analytic expressions of the energy and wave function for the ground state are given. The convergence of the solution is also discussed. The method is applied to the ground state of the heavy quarkonium system.